Elements of Chemical Reaction Engineering, Global Edition
portes grátis
Elements of Chemical Reaction Engineering, Global Edition
Fogler, H.
Pearson Education Limited
02/2022
1080
Mole
Inglês
9781292416663
15 a 20 dias
1800
Descrição não disponível.
Mole Balances 1
The Rate of Reaction, -r_A
The General Mole Balance Equation (GMBE)
Batch Reactors (BRs)
Continuous-Flow Reactors
Industrial Reactors
And Now . . . A Word from Our Sponsor-Safety 1 (AWFOS - S1 Safety)
Conversion and Reactor Sizing
Definition of Conversion
Batch Reactor Design Equations
Design Equations for Flow Reactors
Sizing Continuous-Flow Reactors
Reactors in Series
Some Further Definitions
And Now . . . A Word from Our Sponsor-Safety 2
Rate Laws 75
Basic Definitions
The Rate Law
The Reaction-Rate Constant
Molecular Simulations
Present Status of Our Approach to Reactor Sizing and Design
And Now . . . A Word from Our Sponsor-Safety 3 (AWFOS - S3 The GHS Diamond)
Stoichiometry
Batch Reactors (BRs)
Flow Systems
Reversible Reactions and Equilibrium Conversion
And Now . . . A Word from Our Sponsor-Safety 4 (AWFOS - S4 The Swiss Cheese Model
Isothermal Reactor Design: Conversion
Design Structure for Isothermal Reactors
Batch Reactors (BRs)
Continuous-Stirred Tank Reactors (CSTRs)
Tubular Reactors
Pressure Drop in Reactors
Synthesizing the Design of a Chemical Plant
And Now . . . A Word from Our Sponsor-Safety 5 (AWFOS - S5 A Safety Analysis of the Incident Algorithm)
Isothermal Reactor Design: Moles and Molar Flow Rates
The Moles and Molar Flow Rate Balance Algorithms
Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors
Application of the PFR Molar Flow Rate Algorithm to a Microreactor
Membrane Reactors
Unsteady-State Operation of Stirred Reactors
Semibatch Reactors
And Now . . . A Word from Our Sponsor-Safety 6 (AWFOS - S6 The BowTie Diagram)
Collection and Analysis of Rate Data
The Algorithm for Data Analysis
Determining the Reaction Order for Each of Two Reactants Using the Method of Excess
Integral Method
Differential Method of Analysis
Nonlinear Regression
Reaction-Rate Data from Differential Reactors
Experimental Planning
And Now . . . A Word from Our Sponsor-Safety 7 (AWFOS - S7 Laboratory Safety)
Multiple Reactions
Definitions
Algorithm for Multiple Reactions
Parallel Reactions
Reactions in Series
Complex Reactions
Membrane Reactors to Improve Selectivity in Multiple Reactions
Sorting It All Out
The Fun Part
And Now . . . A Word from Our Sponsor-Safety 8 (AWFOS - S8 The Fire Triangle)
Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors
Active Intermediates and Nonelementary Rate Laws
Enzymatic Reaction Fundamentals
Inhibition of Enzyme Reactions
Bioreactors and Biosynthesis
And Now . . . A Word from Our Sponsor-Safety 9 (AWFOS - S9 Process Safety Triangle)
Catalysis and Catalytic Reactors
Catalysts
Steps in a Catalytic Reaction
Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step
Heterogeneous Data Analysis for Reactor Design
Reaction Engineering in Microelectronic Fabrication
Model Discrimination
Catalyst Deactivation
Reactors That Can Be Used to Help Offset Catalyst Decay
And Now . . . A Word from Our Sponsor-Safety 10 (AWFOS - S10 Exxon Mobil Torrance Refinery Explosion Involving a Straight-Through Transport Reactor [STTR])
Nonisothermal Reactor Design: The Steady-State Energy Balance and Adiabatic PFR Applications
Rationale
The Energy Balance
The User-Friendly Energy Balance Equations
Adiabatic Operation
Adiabatic Equilibrium Conversion
Reactor Staging with Interstage Cooling or Heating
Optimum Feed Temperature
And Now . . . A Word from Our Sponsor-Safety 11 (AWFOS - S11 Acronyms)
Steady-State Nonisothermal Reactor Design: Flow Reactors with Heat Exchange
Steady-State Tubular Reactor with Heat Exchange
Balance on the Heat-Transfer Fluid
Examples of the Algorithm for PFR/PBR Design with Heat Effects
CSTR with Heat Effects
Multiple Steady States (MSS)
Nonisothermal Multiple Chemical Reactions
Radial and Axial Temperature Variations in a Tubular Reactor
And Now . . . A Word from Our Sponsor-Safety 12 (AWFOS - S12 Safety Statistics)
Unsteady-State Nonisothermal Reactor Design
The Unsteady-State Energy Balance
Energy Balance on Batch Reactors (BRs)
Batch and Semibatch Reactors with a Heat Exchanger
Nonisothermal Multiple Reactions
And Now . . . A Word from Our Sponsor-Safety 13 (AWFOS - S13 Safety Analysis of the T2 Laboratories Incident)
Mass Transfer Limitations in Reacting Systems
Diffusion Fundamentals
Binary Diffusion
Modeling Diffusion with Chemical Reaction
The Mass Transfer Coefficient
Mass Transfer to a Single Particle
The Shrinking Core Model
Mass Transfer-Limited Reactions in Packed Beds
Robert the Worrier
What If . . . ? (Parameter Sensitivity)
And Now . . . A Word from Our Sponsor-Safety 14 (AWFOS - S14 Sugar Dust Explosion)
Diffusion and Reaction
Diffusion and Reactions in Homogeneous Systems
Diffusion and Reactions in Spherical Catalyst Pellets
The Internal Effectiveness Factor
Falsified Kinetics
Overall Effectiveness Factor
Estimation of Diffusion- and Reaction-Limited Regimes
Mass Transfer and Reaction in a Packed Bed
Determination of Limiting Situations from Reaction-Rate Data
Multiphase Reactors in the Professional Reference Shelf
Fluidized Bed Reactors
Chemical Vapor Deposition (CVD)
And Now . . . A Word from Our Sponsor-Safety 15 (AWFOS - S15 Critical Thinking Questions Applied to Safety)
Residence Time Distributions of Chemical Reactors
General Considerations
Measurement of the RTD
Characteristics of the RTD
RTD in Ideal Reactors
PFR/CSTR Series RTD
Diagnostics and TroubleshootingAnd Now . . . A Word from Our Sponsor-Safety 16 (AWFOS - S16 Critical Thinking Actions)
Predicting Conversion Directly from the Residence Time Distribution
Modeling Nonideal Reactors Using the RTD
Zero Adjustable Parameter Models
Using Software Packages Such as Polymath to Find Maximum Mixedness Conversion
Tanks-in-Series One Parameter Model, n
RTD and Multiple Reactions
And Now . . . A Word from Our Sponsor-Safety 17 (AWFOS - S17 Brief Case History on an Air Preheater)
Models for Nonideal Reactors
Some Guidelines for Developing Models
Flow and Axial Dispersion of Inert Tracers in Isothermal Reactors
Flow, Reaction, and Axial Dispersion
Flow, Reaction, and Axial Dispersion in Isothermal Laminar-Flow Reactors and Finding Meno
Tanks-in-Series Model versus Dispersion Model
Numerical Solutions to Flows with Dispersion and Reaction
Nonisothermal Flow with Radial and Axial Variations in a Tubular Reactor
Two-Parameter Models-Modeling Real Reactors with Combinations of Ideal Reactors
And Now . . . A Word from Our Sponsor-Safety 18 (AWFOS - S18 An Algorithm for Management of Change (MoC))
Appendix A: Numerical Techniques
A.1 Useful Integrals in Chemical Reactor Design
A.2 Equal-Area Graphical Differentiation
A.3 Solutions to Differential Equations
A.4 Numerical Evaluation of Integrals
A.5 Semi-Log Graphs
A.6 Software Packages
Appendix B: Ideal Gas Constant and Conversion Factors Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant Appendix D: Software Packages
D.1 Polymath
D.2 Wolfram
D.3 Python
D.4 MATLAB
D.5 Excel
D.6 COMSOL (http://www.umich.edu/~elements/6e/12chap/comsol.html)
D.7 Aspen
D.8 Visual Encyclopedia of Equipment: Reactors Section
D.9 Reactor Lab
Appendix E: Rate-Law Data Appendix F: Nomenclature Appendix G: Open-Ended Problems
G.1 Chem-E-Car
G.2 Effective Lubricant Design
G.3 Peach Bottom Nuclear Reactor
G.4 Underground Wet Oxidation
G.5 Hydrodesulfurization Reactor Design
G.6 Continuous Bioprocessing
G.7 Methanol Synthesis
G.8 Cajun Seafood Gumbo
G.9 Alcohol Metabolism
G.10 Methanol Poisoning
G.11 Safety
Appendix H: Use of Computational Chemistry Software Packages
H.1 Computational Chemical Reaction Engineering
Appendix I: How to Use the CRE Web Resources
I.1 CRE Web Resources Components
Index
The Rate of Reaction, -r_A
The General Mole Balance Equation (GMBE)
Batch Reactors (BRs)
Continuous-Flow Reactors
Industrial Reactors
And Now . . . A Word from Our Sponsor-Safety 1 (AWFOS - S1 Safety)
Conversion and Reactor Sizing
Definition of Conversion
Batch Reactor Design Equations
Design Equations for Flow Reactors
Sizing Continuous-Flow Reactors
Reactors in Series
Some Further Definitions
And Now . . . A Word from Our Sponsor-Safety 2
Rate Laws 75
Basic Definitions
The Rate Law
The Reaction-Rate Constant
Molecular Simulations
Present Status of Our Approach to Reactor Sizing and Design
And Now . . . A Word from Our Sponsor-Safety 3 (AWFOS - S3 The GHS Diamond)
Stoichiometry
Batch Reactors (BRs)
Flow Systems
Reversible Reactions and Equilibrium Conversion
And Now . . . A Word from Our Sponsor-Safety 4 (AWFOS - S4 The Swiss Cheese Model
Isothermal Reactor Design: Conversion
Design Structure for Isothermal Reactors
Batch Reactors (BRs)
Continuous-Stirred Tank Reactors (CSTRs)
Tubular Reactors
Pressure Drop in Reactors
Synthesizing the Design of a Chemical Plant
And Now . . . A Word from Our Sponsor-Safety 5 (AWFOS - S5 A Safety Analysis of the Incident Algorithm)
Isothermal Reactor Design: Moles and Molar Flow Rates
The Moles and Molar Flow Rate Balance Algorithms
Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors
Application of the PFR Molar Flow Rate Algorithm to a Microreactor
Membrane Reactors
Unsteady-State Operation of Stirred Reactors
Semibatch Reactors
And Now . . . A Word from Our Sponsor-Safety 6 (AWFOS - S6 The BowTie Diagram)
Collection and Analysis of Rate Data
The Algorithm for Data Analysis
Determining the Reaction Order for Each of Two Reactants Using the Method of Excess
Integral Method
Differential Method of Analysis
Nonlinear Regression
Reaction-Rate Data from Differential Reactors
Experimental Planning
And Now . . . A Word from Our Sponsor-Safety 7 (AWFOS - S7 Laboratory Safety)
Multiple Reactions
Definitions
Algorithm for Multiple Reactions
Parallel Reactions
Reactions in Series
Complex Reactions
Membrane Reactors to Improve Selectivity in Multiple Reactions
Sorting It All Out
The Fun Part
And Now . . . A Word from Our Sponsor-Safety 8 (AWFOS - S8 The Fire Triangle)
Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors
Active Intermediates and Nonelementary Rate Laws
Enzymatic Reaction Fundamentals
Inhibition of Enzyme Reactions
Bioreactors and Biosynthesis
And Now . . . A Word from Our Sponsor-Safety 9 (AWFOS - S9 Process Safety Triangle)
Catalysis and Catalytic Reactors
Catalysts
Steps in a Catalytic Reaction
Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step
Heterogeneous Data Analysis for Reactor Design
Reaction Engineering in Microelectronic Fabrication
Model Discrimination
Catalyst Deactivation
Reactors That Can Be Used to Help Offset Catalyst Decay
And Now . . . A Word from Our Sponsor-Safety 10 (AWFOS - S10 Exxon Mobil Torrance Refinery Explosion Involving a Straight-Through Transport Reactor [STTR])
Nonisothermal Reactor Design: The Steady-State Energy Balance and Adiabatic PFR Applications
Rationale
The Energy Balance
The User-Friendly Energy Balance Equations
Adiabatic Operation
Adiabatic Equilibrium Conversion
Reactor Staging with Interstage Cooling or Heating
Optimum Feed Temperature
And Now . . . A Word from Our Sponsor-Safety 11 (AWFOS - S11 Acronyms)
Steady-State Nonisothermal Reactor Design: Flow Reactors with Heat Exchange
Steady-State Tubular Reactor with Heat Exchange
Balance on the Heat-Transfer Fluid
Examples of the Algorithm for PFR/PBR Design with Heat Effects
CSTR with Heat Effects
Multiple Steady States (MSS)
Nonisothermal Multiple Chemical Reactions
Radial and Axial Temperature Variations in a Tubular Reactor
And Now . . . A Word from Our Sponsor-Safety 12 (AWFOS - S12 Safety Statistics)
Unsteady-State Nonisothermal Reactor Design
The Unsteady-State Energy Balance
Energy Balance on Batch Reactors (BRs)
Batch and Semibatch Reactors with a Heat Exchanger
Nonisothermal Multiple Reactions
And Now . . . A Word from Our Sponsor-Safety 13 (AWFOS - S13 Safety Analysis of the T2 Laboratories Incident)
Mass Transfer Limitations in Reacting Systems
Diffusion Fundamentals
Binary Diffusion
Modeling Diffusion with Chemical Reaction
The Mass Transfer Coefficient
Mass Transfer to a Single Particle
The Shrinking Core Model
Mass Transfer-Limited Reactions in Packed Beds
Robert the Worrier
What If . . . ? (Parameter Sensitivity)
And Now . . . A Word from Our Sponsor-Safety 14 (AWFOS - S14 Sugar Dust Explosion)
Diffusion and Reaction
Diffusion and Reactions in Homogeneous Systems
Diffusion and Reactions in Spherical Catalyst Pellets
The Internal Effectiveness Factor
Falsified Kinetics
Overall Effectiveness Factor
Estimation of Diffusion- and Reaction-Limited Regimes
Mass Transfer and Reaction in a Packed Bed
Determination of Limiting Situations from Reaction-Rate Data
Multiphase Reactors in the Professional Reference Shelf
Fluidized Bed Reactors
Chemical Vapor Deposition (CVD)
And Now . . . A Word from Our Sponsor-Safety 15 (AWFOS - S15 Critical Thinking Questions Applied to Safety)
Residence Time Distributions of Chemical Reactors
General Considerations
Measurement of the RTD
Characteristics of the RTD
RTD in Ideal Reactors
PFR/CSTR Series RTD
Diagnostics and TroubleshootingAnd Now . . . A Word from Our Sponsor-Safety 16 (AWFOS - S16 Critical Thinking Actions)
Predicting Conversion Directly from the Residence Time Distribution
Modeling Nonideal Reactors Using the RTD
Zero Adjustable Parameter Models
Using Software Packages Such as Polymath to Find Maximum Mixedness Conversion
Tanks-in-Series One Parameter Model, n
RTD and Multiple Reactions
And Now . . . A Word from Our Sponsor-Safety 17 (AWFOS - S17 Brief Case History on an Air Preheater)
Models for Nonideal Reactors
Some Guidelines for Developing Models
Flow and Axial Dispersion of Inert Tracers in Isothermal Reactors
Flow, Reaction, and Axial Dispersion
Flow, Reaction, and Axial Dispersion in Isothermal Laminar-Flow Reactors and Finding Meno
Tanks-in-Series Model versus Dispersion Model
Numerical Solutions to Flows with Dispersion and Reaction
Nonisothermal Flow with Radial and Axial Variations in a Tubular Reactor
Two-Parameter Models-Modeling Real Reactors with Combinations of Ideal Reactors
And Now . . . A Word from Our Sponsor-Safety 18 (AWFOS - S18 An Algorithm for Management of Change (MoC))
Appendix A: Numerical Techniques
A.1 Useful Integrals in Chemical Reactor Design
A.2 Equal-Area Graphical Differentiation
A.3 Solutions to Differential Equations
A.4 Numerical Evaluation of Integrals
A.5 Semi-Log Graphs
A.6 Software Packages
Appendix B: Ideal Gas Constant and Conversion Factors Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant Appendix D: Software Packages
D.1 Polymath
D.2 Wolfram
D.3 Python
D.4 MATLAB
D.5 Excel
D.6 COMSOL (http://www.umich.edu/~elements/6e/12chap/comsol.html)
D.7 Aspen
D.8 Visual Encyclopedia of Equipment: Reactors Section
D.9 Reactor Lab
Appendix E: Rate-Law Data Appendix F: Nomenclature Appendix G: Open-Ended Problems
G.1 Chem-E-Car
G.2 Effective Lubricant Design
G.3 Peach Bottom Nuclear Reactor
G.4 Underground Wet Oxidation
G.5 Hydrodesulfurization Reactor Design
G.6 Continuous Bioprocessing
G.7 Methanol Synthesis
G.8 Cajun Seafood Gumbo
G.9 Alcohol Metabolism
G.10 Methanol Poisoning
G.11 Safety
Appendix H: Use of Computational Chemistry Software Packages
H.1 Computational Chemical Reaction Engineering
Appendix I: How to Use the CRE Web Resources
I.1 CRE Web Resources Components
Index
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chemical reaction engineering; kinetics; chemical reactors; chemical engineering; bioreactors; reactor design; catalytic reactors; Scott Fogler; Fogler; Folger + chemical engineering; chemical engineering + safety; industrial chemistry
Mole Balances 1
The Rate of Reaction, -r_A
The General Mole Balance Equation (GMBE)
Batch Reactors (BRs)
Continuous-Flow Reactors
Industrial Reactors
And Now . . . A Word from Our Sponsor-Safety 1 (AWFOS - S1 Safety)
Conversion and Reactor Sizing
Definition of Conversion
Batch Reactor Design Equations
Design Equations for Flow Reactors
Sizing Continuous-Flow Reactors
Reactors in Series
Some Further Definitions
And Now . . . A Word from Our Sponsor-Safety 2
Rate Laws 75
Basic Definitions
The Rate Law
The Reaction-Rate Constant
Molecular Simulations
Present Status of Our Approach to Reactor Sizing and Design
And Now . . . A Word from Our Sponsor-Safety 3 (AWFOS - S3 The GHS Diamond)
Stoichiometry
Batch Reactors (BRs)
Flow Systems
Reversible Reactions and Equilibrium Conversion
And Now . . . A Word from Our Sponsor-Safety 4 (AWFOS - S4 The Swiss Cheese Model
Isothermal Reactor Design: Conversion
Design Structure for Isothermal Reactors
Batch Reactors (BRs)
Continuous-Stirred Tank Reactors (CSTRs)
Tubular Reactors
Pressure Drop in Reactors
Synthesizing the Design of a Chemical Plant
And Now . . . A Word from Our Sponsor-Safety 5 (AWFOS - S5 A Safety Analysis of the Incident Algorithm)
Isothermal Reactor Design: Moles and Molar Flow Rates
The Moles and Molar Flow Rate Balance Algorithms
Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors
Application of the PFR Molar Flow Rate Algorithm to a Microreactor
Membrane Reactors
Unsteady-State Operation of Stirred Reactors
Semibatch Reactors
And Now . . . A Word from Our Sponsor-Safety 6 (AWFOS - S6 The BowTie Diagram)
Collection and Analysis of Rate Data
The Algorithm for Data Analysis
Determining the Reaction Order for Each of Two Reactants Using the Method of Excess
Integral Method
Differential Method of Analysis
Nonlinear Regression
Reaction-Rate Data from Differential Reactors
Experimental Planning
And Now . . . A Word from Our Sponsor-Safety 7 (AWFOS - S7 Laboratory Safety)
Multiple Reactions
Definitions
Algorithm for Multiple Reactions
Parallel Reactions
Reactions in Series
Complex Reactions
Membrane Reactors to Improve Selectivity in Multiple Reactions
Sorting It All Out
The Fun Part
And Now . . . A Word from Our Sponsor-Safety 8 (AWFOS - S8 The Fire Triangle)
Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors
Active Intermediates and Nonelementary Rate Laws
Enzymatic Reaction Fundamentals
Inhibition of Enzyme Reactions
Bioreactors and Biosynthesis
And Now . . . A Word from Our Sponsor-Safety 9 (AWFOS - S9 Process Safety Triangle)
Catalysis and Catalytic Reactors
Catalysts
Steps in a Catalytic Reaction
Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step
Heterogeneous Data Analysis for Reactor Design
Reaction Engineering in Microelectronic Fabrication
Model Discrimination
Catalyst Deactivation
Reactors That Can Be Used to Help Offset Catalyst Decay
And Now . . . A Word from Our Sponsor-Safety 10 (AWFOS - S10 Exxon Mobil Torrance Refinery Explosion Involving a Straight-Through Transport Reactor [STTR])
Nonisothermal Reactor Design: The Steady-State Energy Balance and Adiabatic PFR Applications
Rationale
The Energy Balance
The User-Friendly Energy Balance Equations
Adiabatic Operation
Adiabatic Equilibrium Conversion
Reactor Staging with Interstage Cooling or Heating
Optimum Feed Temperature
And Now . . . A Word from Our Sponsor-Safety 11 (AWFOS - S11 Acronyms)
Steady-State Nonisothermal Reactor Design: Flow Reactors with Heat Exchange
Steady-State Tubular Reactor with Heat Exchange
Balance on the Heat-Transfer Fluid
Examples of the Algorithm for PFR/PBR Design with Heat Effects
CSTR with Heat Effects
Multiple Steady States (MSS)
Nonisothermal Multiple Chemical Reactions
Radial and Axial Temperature Variations in a Tubular Reactor
And Now . . . A Word from Our Sponsor-Safety 12 (AWFOS - S12 Safety Statistics)
Unsteady-State Nonisothermal Reactor Design
The Unsteady-State Energy Balance
Energy Balance on Batch Reactors (BRs)
Batch and Semibatch Reactors with a Heat Exchanger
Nonisothermal Multiple Reactions
And Now . . . A Word from Our Sponsor-Safety 13 (AWFOS - S13 Safety Analysis of the T2 Laboratories Incident)
Mass Transfer Limitations in Reacting Systems
Diffusion Fundamentals
Binary Diffusion
Modeling Diffusion with Chemical Reaction
The Mass Transfer Coefficient
Mass Transfer to a Single Particle
The Shrinking Core Model
Mass Transfer-Limited Reactions in Packed Beds
Robert the Worrier
What If . . . ? (Parameter Sensitivity)
And Now . . . A Word from Our Sponsor-Safety 14 (AWFOS - S14 Sugar Dust Explosion)
Diffusion and Reaction
Diffusion and Reactions in Homogeneous Systems
Diffusion and Reactions in Spherical Catalyst Pellets
The Internal Effectiveness Factor
Falsified Kinetics
Overall Effectiveness Factor
Estimation of Diffusion- and Reaction-Limited Regimes
Mass Transfer and Reaction in a Packed Bed
Determination of Limiting Situations from Reaction-Rate Data
Multiphase Reactors in the Professional Reference Shelf
Fluidized Bed Reactors
Chemical Vapor Deposition (CVD)
And Now . . . A Word from Our Sponsor-Safety 15 (AWFOS - S15 Critical Thinking Questions Applied to Safety)
Residence Time Distributions of Chemical Reactors
General Considerations
Measurement of the RTD
Characteristics of the RTD
RTD in Ideal Reactors
PFR/CSTR Series RTD
Diagnostics and TroubleshootingAnd Now . . . A Word from Our Sponsor-Safety 16 (AWFOS - S16 Critical Thinking Actions)
Predicting Conversion Directly from the Residence Time Distribution
Modeling Nonideal Reactors Using the RTD
Zero Adjustable Parameter Models
Using Software Packages Such as Polymath to Find Maximum Mixedness Conversion
Tanks-in-Series One Parameter Model, n
RTD and Multiple Reactions
And Now . . . A Word from Our Sponsor-Safety 17 (AWFOS - S17 Brief Case History on an Air Preheater)
Models for Nonideal Reactors
Some Guidelines for Developing Models
Flow and Axial Dispersion of Inert Tracers in Isothermal Reactors
Flow, Reaction, and Axial Dispersion
Flow, Reaction, and Axial Dispersion in Isothermal Laminar-Flow Reactors and Finding Meno
Tanks-in-Series Model versus Dispersion Model
Numerical Solutions to Flows with Dispersion and Reaction
Nonisothermal Flow with Radial and Axial Variations in a Tubular Reactor
Two-Parameter Models-Modeling Real Reactors with Combinations of Ideal Reactors
And Now . . . A Word from Our Sponsor-Safety 18 (AWFOS - S18 An Algorithm for Management of Change (MoC))
Appendix A: Numerical Techniques
A.1 Useful Integrals in Chemical Reactor Design
A.2 Equal-Area Graphical Differentiation
A.3 Solutions to Differential Equations
A.4 Numerical Evaluation of Integrals
A.5 Semi-Log Graphs
A.6 Software Packages
Appendix B: Ideal Gas Constant and Conversion Factors Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant Appendix D: Software Packages
D.1 Polymath
D.2 Wolfram
D.3 Python
D.4 MATLAB
D.5 Excel
D.6 COMSOL (http://www.umich.edu/~elements/6e/12chap/comsol.html)
D.7 Aspen
D.8 Visual Encyclopedia of Equipment: Reactors Section
D.9 Reactor Lab
Appendix E: Rate-Law Data Appendix F: Nomenclature Appendix G: Open-Ended Problems
G.1 Chem-E-Car
G.2 Effective Lubricant Design
G.3 Peach Bottom Nuclear Reactor
G.4 Underground Wet Oxidation
G.5 Hydrodesulfurization Reactor Design
G.6 Continuous Bioprocessing
G.7 Methanol Synthesis
G.8 Cajun Seafood Gumbo
G.9 Alcohol Metabolism
G.10 Methanol Poisoning
G.11 Safety
Appendix H: Use of Computational Chemistry Software Packages
H.1 Computational Chemical Reaction Engineering
Appendix I: How to Use the CRE Web Resources
I.1 CRE Web Resources Components
Index
The Rate of Reaction, -r_A
The General Mole Balance Equation (GMBE)
Batch Reactors (BRs)
Continuous-Flow Reactors
Industrial Reactors
And Now . . . A Word from Our Sponsor-Safety 1 (AWFOS - S1 Safety)
Conversion and Reactor Sizing
Definition of Conversion
Batch Reactor Design Equations
Design Equations for Flow Reactors
Sizing Continuous-Flow Reactors
Reactors in Series
Some Further Definitions
And Now . . . A Word from Our Sponsor-Safety 2
Rate Laws 75
Basic Definitions
The Rate Law
The Reaction-Rate Constant
Molecular Simulations
Present Status of Our Approach to Reactor Sizing and Design
And Now . . . A Word from Our Sponsor-Safety 3 (AWFOS - S3 The GHS Diamond)
Stoichiometry
Batch Reactors (BRs)
Flow Systems
Reversible Reactions and Equilibrium Conversion
And Now . . . A Word from Our Sponsor-Safety 4 (AWFOS - S4 The Swiss Cheese Model
Isothermal Reactor Design: Conversion
Design Structure for Isothermal Reactors
Batch Reactors (BRs)
Continuous-Stirred Tank Reactors (CSTRs)
Tubular Reactors
Pressure Drop in Reactors
Synthesizing the Design of a Chemical Plant
And Now . . . A Word from Our Sponsor-Safety 5 (AWFOS - S5 A Safety Analysis of the Incident Algorithm)
Isothermal Reactor Design: Moles and Molar Flow Rates
The Moles and Molar Flow Rate Balance Algorithms
Mole Balances on CSTRs, PFRs, PBRs, and Batch Reactors
Application of the PFR Molar Flow Rate Algorithm to a Microreactor
Membrane Reactors
Unsteady-State Operation of Stirred Reactors
Semibatch Reactors
And Now . . . A Word from Our Sponsor-Safety 6 (AWFOS - S6 The BowTie Diagram)
Collection and Analysis of Rate Data
The Algorithm for Data Analysis
Determining the Reaction Order for Each of Two Reactants Using the Method of Excess
Integral Method
Differential Method of Analysis
Nonlinear Regression
Reaction-Rate Data from Differential Reactors
Experimental Planning
And Now . . . A Word from Our Sponsor-Safety 7 (AWFOS - S7 Laboratory Safety)
Multiple Reactions
Definitions
Algorithm for Multiple Reactions
Parallel Reactions
Reactions in Series
Complex Reactions
Membrane Reactors to Improve Selectivity in Multiple Reactions
Sorting It All Out
The Fun Part
And Now . . . A Word from Our Sponsor-Safety 8 (AWFOS - S8 The Fire Triangle)
Reaction Mechanisms, Pathways, Bioreactions, and Bioreactors
Active Intermediates and Nonelementary Rate Laws
Enzymatic Reaction Fundamentals
Inhibition of Enzyme Reactions
Bioreactors and Biosynthesis
And Now . . . A Word from Our Sponsor-Safety 9 (AWFOS - S9 Process Safety Triangle)
Catalysis and Catalytic Reactors
Catalysts
Steps in a Catalytic Reaction
Synthesizing a Rate Law, Mechanism, and Rate-Limiting Step
Heterogeneous Data Analysis for Reactor Design
Reaction Engineering in Microelectronic Fabrication
Model Discrimination
Catalyst Deactivation
Reactors That Can Be Used to Help Offset Catalyst Decay
And Now . . . A Word from Our Sponsor-Safety 10 (AWFOS - S10 Exxon Mobil Torrance Refinery Explosion Involving a Straight-Through Transport Reactor [STTR])
Nonisothermal Reactor Design: The Steady-State Energy Balance and Adiabatic PFR Applications
Rationale
The Energy Balance
The User-Friendly Energy Balance Equations
Adiabatic Operation
Adiabatic Equilibrium Conversion
Reactor Staging with Interstage Cooling or Heating
Optimum Feed Temperature
And Now . . . A Word from Our Sponsor-Safety 11 (AWFOS - S11 Acronyms)
Steady-State Nonisothermal Reactor Design: Flow Reactors with Heat Exchange
Steady-State Tubular Reactor with Heat Exchange
Balance on the Heat-Transfer Fluid
Examples of the Algorithm for PFR/PBR Design with Heat Effects
CSTR with Heat Effects
Multiple Steady States (MSS)
Nonisothermal Multiple Chemical Reactions
Radial and Axial Temperature Variations in a Tubular Reactor
And Now . . . A Word from Our Sponsor-Safety 12 (AWFOS - S12 Safety Statistics)
Unsteady-State Nonisothermal Reactor Design
The Unsteady-State Energy Balance
Energy Balance on Batch Reactors (BRs)
Batch and Semibatch Reactors with a Heat Exchanger
Nonisothermal Multiple Reactions
And Now . . . A Word from Our Sponsor-Safety 13 (AWFOS - S13 Safety Analysis of the T2 Laboratories Incident)
Mass Transfer Limitations in Reacting Systems
Diffusion Fundamentals
Binary Diffusion
Modeling Diffusion with Chemical Reaction
The Mass Transfer Coefficient
Mass Transfer to a Single Particle
The Shrinking Core Model
Mass Transfer-Limited Reactions in Packed Beds
Robert the Worrier
What If . . . ? (Parameter Sensitivity)
And Now . . . A Word from Our Sponsor-Safety 14 (AWFOS - S14 Sugar Dust Explosion)
Diffusion and Reaction
Diffusion and Reactions in Homogeneous Systems
Diffusion and Reactions in Spherical Catalyst Pellets
The Internal Effectiveness Factor
Falsified Kinetics
Overall Effectiveness Factor
Estimation of Diffusion- and Reaction-Limited Regimes
Mass Transfer and Reaction in a Packed Bed
Determination of Limiting Situations from Reaction-Rate Data
Multiphase Reactors in the Professional Reference Shelf
Fluidized Bed Reactors
Chemical Vapor Deposition (CVD)
And Now . . . A Word from Our Sponsor-Safety 15 (AWFOS - S15 Critical Thinking Questions Applied to Safety)
Residence Time Distributions of Chemical Reactors
General Considerations
Measurement of the RTD
Characteristics of the RTD
RTD in Ideal Reactors
PFR/CSTR Series RTD
Diagnostics and TroubleshootingAnd Now . . . A Word from Our Sponsor-Safety 16 (AWFOS - S16 Critical Thinking Actions)
Predicting Conversion Directly from the Residence Time Distribution
Modeling Nonideal Reactors Using the RTD
Zero Adjustable Parameter Models
Using Software Packages Such as Polymath to Find Maximum Mixedness Conversion
Tanks-in-Series One Parameter Model, n
RTD and Multiple Reactions
And Now . . . A Word from Our Sponsor-Safety 17 (AWFOS - S17 Brief Case History on an Air Preheater)
Models for Nonideal Reactors
Some Guidelines for Developing Models
Flow and Axial Dispersion of Inert Tracers in Isothermal Reactors
Flow, Reaction, and Axial Dispersion
Flow, Reaction, and Axial Dispersion in Isothermal Laminar-Flow Reactors and Finding Meno
Tanks-in-Series Model versus Dispersion Model
Numerical Solutions to Flows with Dispersion and Reaction
Nonisothermal Flow with Radial and Axial Variations in a Tubular Reactor
Two-Parameter Models-Modeling Real Reactors with Combinations of Ideal Reactors
And Now . . . A Word from Our Sponsor-Safety 18 (AWFOS - S18 An Algorithm for Management of Change (MoC))
Appendix A: Numerical Techniques
A.1 Useful Integrals in Chemical Reactor Design
A.2 Equal-Area Graphical Differentiation
A.3 Solutions to Differential Equations
A.4 Numerical Evaluation of Integrals
A.5 Semi-Log Graphs
A.6 Software Packages
Appendix B: Ideal Gas Constant and Conversion Factors Appendix C: Thermodynamic Relationships Involving the Equilibrium Constant Appendix D: Software Packages
D.1 Polymath
D.2 Wolfram
D.3 Python
D.4 MATLAB
D.5 Excel
D.6 COMSOL (http://www.umich.edu/~elements/6e/12chap/comsol.html)
D.7 Aspen
D.8 Visual Encyclopedia of Equipment: Reactors Section
D.9 Reactor Lab
Appendix E: Rate-Law Data Appendix F: Nomenclature Appendix G: Open-Ended Problems
G.1 Chem-E-Car
G.2 Effective Lubricant Design
G.3 Peach Bottom Nuclear Reactor
G.4 Underground Wet Oxidation
G.5 Hydrodesulfurization Reactor Design
G.6 Continuous Bioprocessing
G.7 Methanol Synthesis
G.8 Cajun Seafood Gumbo
G.9 Alcohol Metabolism
G.10 Methanol Poisoning
G.11 Safety
Appendix H: Use of Computational Chemistry Software Packages
H.1 Computational Chemical Reaction Engineering
Appendix I: How to Use the CRE Web Resources
I.1 CRE Web Resources Components
Index
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