Novel Luminescent Crystalline Materials of Gold(I) Complexes with Stimuli-Responsive Properties

1. General Introduction.- 2. Introduction of a Biphenyl Moiety for a Solvent Responsive Aryl Gold(I).- 3. Luminescent Mechanochromism of a Chiral Complex: Distinct Crystal Structures and Color Changes of Racemic and Homochiral Gold(I) Isocyanide Complexes with a Binaphthyl Moiety.- 4. Mechano-Responsive Luminescence via Crystal-to-Crystal Phase Transitions between Chiral and Non-Chiral Space Groups.- 5. Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color.- 6. Thermo-Responsive Phosphorescence Control Mediated by Molecular Rotation and Aurophilic Interactions in Amphidynamic Crystals of Phosphane-Gold(I) Complex.- 7. Conclusion.

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• Química física
• Química inorgânica
• Química organometálica
• Dispositivos e materiais electrónicos

Luminescent Gold(I) Complex;External Stimuli-responsive Luminescence;Crystal-to-Crystal Phase Transition;Mechano-Responsive Luminescence;Thermo-Responsive Phosphorescence;Molecular Rotor